Helium ppm to mbar*l/s conversion for Fug. Em.'s
In order to perform Fugitive Emissions tests, we use a VARIAN sniffer probe helium leak detector, which gives readings in mbar*l/s. Our usual European reference specification (Shell MESC SPE 77/312) also gives limits in the same measurement unit.
First of all, is anybody able to explain the physical meaning of "mbar*l/s"? Is that a flow rate or a concentration?
Then, how is it possible to relate this with "ppm"? As many leak detectors manufacturers have instruments with both scales, we think there must be a simple relation between the two units.
The Varian 979 cannot measure the flow rate of the gas coming in and
thus cannot count the helium passing through and simply state the
concentration reading or "PPM"
However a smaller test device also
From varian, the Helitest, can. The Helitest allways has the same fow
rate of gas being aspired so measuring the quantity of He atoms makes
that the instrument can detect concentrations "PPM".
mbar l /sec
or I prefer to have the reading in atm cc /sec means that at one
atmosphere pressure there are X cc of helium atoms passing per second
through the machine.
THERE IS NO CONVERSION POSSIBLE BETWEEN mbar
l / sec, atm cc / sec and PPM/filter. One is a flow reading and the other is a
concentration reading. There are tricks to establish a link but they
are empiric and have no scientific basis.
The Varian 979 has a callibrated leak source internal.
At
start the unit wil self callibrate. in fact what it does is it lets
the callibrated leak pass through the unit. ionises the helium atoms and
separates them off with a magnetic field. the helium atoms fall on a
capturing electrode and create a small current. The machine then
establishes that this current is equal to the flow rate of the
callibrated leak.
When in sniffing mode the machine will draw in
helium atoms and see how many atoms pass through the unit by measuring
the detection electrode amperage.
Allow me to continue later Lunch break is over.
When the unit self calibrates all of the leakage from the calibrated leak source passes through the instrument.
When sniffing helium only a part of the leakage that is coming from the leakage source passes through the instrument.
When
one calibrates the instrument with a calibrated leak source of say
1.7E-8 atm.cc./sec. we are sure that all the helium leaked passed
through the machine.
Now it depends on the method of measurement whether or not we will be measuring all the leakage.
Method TA Luft; good old German Grundlig und Punktlich.
The
leak source is completely encapsulated and all leaking gasses are
passed through the leak detector. This is great, all leak gass is
detected and we can determine how much helium has escaped into the
atmosphere.
Method 21: EPA Uncle Sams way; a sniffer with a
determined opening cross section is placed at a location 5 mm from the
leak source and parts of any whiffs of Helium that are leaking out pass
through the leak detector. We can only guess at which percentage of the
leakage is captured.
Method TA luft may be good and correct but
as many times is the cases with our German friends it is
impractical. Who would like to go out and make 5000 adaptors to be able
to sniff all the leakage in a chemical plant.
Method
21 is inaccurate but practical. the idea I guess is that if you
standardise on the way and the instruments with which to measure you
will be able to pick up trends. And also it is easy to equip a helium
detector with a correct sniffer and a distance spacer and to go out
measure 5000 valves in a plant.
One more thing: Helium intake by a
varian leak detector is influenced by pressure and temperature. the
detector compensates for temperature changes since the last self
callibration. I still need to get from Varian whether the detector
compensates for pressure changes also.
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